锑物质欧盟REACH注册视频会议于9月举行
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A webinar on
Antimony EU REACH Registration
was held
in September 2010.
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Classification and labelling of Sodium Hexahydroxoantimonate

Classification and labelling according to CLP/GHS

Remarks: The classification and labelling of sodium hexahydroxoantimonate is covered by a group entry in Annex VI of regulation (EC) 1272/2008, Index No. 051-003-00-9.

However, recently generated substance specific hazard data do not support the harmonised classification and labelling for this antimony compound as stated in Annex VI of regulation (EC) 1272/2008.

Therefore, an alternative proposal for the classification and labelling of sodium hexahydroxoantimonate based on substance specific data is provided as well.

Sodium Hexahydroxoantimonate (Representative sample)

State/form of the substance: powder

Classification

Acute Tox. 4 (H302, H332)

Aquatic Chronic 2 (H411)

Labelling
Signal word Warning
Hazard pictogram

GHS07: exclamation mark

EXCLAMATION MARK

GHS09: environment

ENVIRONMENT

Hazard statements

H332: Harmful if inhaled.

H302: Harmful if swallowed.

H411: Toxic to aquatic life with long lasting effects.

Precautionary statements

P261: Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P273: Avoid release to the environment.

P391: Collect spillage.

P501: Dispose of contents/container to in accordance with local regulations

Notes

Note A, Note 1

Sodium Hexahydroxoantimonate (Representative sample) - proposed alternative classification

State/form of the substance: powder

Remarks: Proposal for non-classification and labelling based on substance-specific, guideline-conform experimental data with unrestricted reliability as given in the technical dossier.

No classification, so no labelling.

Classification and labelling according to DSD (Annex I of Directive 67/548/EEC)

Remarks: The classification and labelling of sodium hexahydroxoantimonate is covered by a group entry in Annex VI of regulation (EC) 1272/2008, Index No. 051-003-00-9.

However, recently generated substance specific hazard data do not support the harmonised classification and labelling for this antimony compound as stated in Annex VI of regulation (EC) 1272/2008.

Therefore, an alternative proposal for the classification and labelling of sodium hexahydroxoantimonate based on substance specific data is provided as well.

Sodium Hexahydroxoantimonate (Representative sample)

Classification

Xn; R20/22

N; R51/53

Labelling
Indication of danger

Xn - harmful

N - dangerous for the environment

R-phrases

R20/22 - harmful by inhalation and if swallowed

R51/53 - toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

S-phrases

S2 - keep out of the reach of children

S61 - avoid release to the environment. refer to special instructions/safety data sheets

Notes

Note A, Note 1

Sodium Hexahydroxoantimonate (Representative sample) - proposed alternative classification

Remarks: Proposal for non-classification and labelling based on substance-specific, guideline-conform experimental data with unrestricted reliability as given in the technical dossier.

Classification

N; R51/53

Labelling
Indication of danger

N - dangerous for the environment

R-phrases

R51/53 - toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

S-phrases

S61 - avoid release to the environment. refer to special instructions/safety data sheets

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