锑物质欧盟REACH注册视频会议于9月举行
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A webinar on
Antimony EU REACH Registration
was held
in September 2010.
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Classification and labelling of Sodium Hexahydroxoantimonate
Classification and labelling according to CLP/GHS
Remarks: The classification and labelling of sodium hexahydroxoantimonate is covered by a group entry in Annex VI of regulation (EC) 1272/2008, Index No. 051-003-00-9.
However, recently generated substance specific hazard data do not support the harmonised classification and labelling for this antimony compound as stated in Annex VI of regulation (EC) 1272/2008.
Therefore, an alternative proposal for the classification and labelling of sodium hexahydroxoantimonate based on substance specific data is provided as well.
Sodium Hexahydroxoantimonate (Representative sample)
State/form of the substance: powder
| Classification |
|---|
Acute Tox. 4 (H302, H332) Aquatic Chronic 2 (H411) |
| Labelling | |
|---|---|
| Signal word | Warning |
| Hazard pictogram | GHS07: exclamation mark
GHS09: environment
|
| Hazard statements | H332: Harmful if inhaled. H302: Harmful if swallowed. H411: Toxic to aquatic life with long lasting effects. |
| Precautionary statements | P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to in accordance with local regulations |
| Notes | Note A, Note 1 |
Sodium Hexahydroxoantimonate (Representative sample) - proposed alternative classification
State/form of the substance: powder
Remarks: Proposal for non-classification and labelling based on substance-specific, guideline-conform experimental data with unrestricted reliability as given in the technical dossier.
No classification, so no labelling.
Classification and labelling according to DSD (Annex I of Directive 67/548/EEC)
Remarks: The classification and labelling of sodium hexahydroxoantimonate is covered by a group entry in Annex VI of regulation (EC) 1272/2008, Index No. 051-003-00-9.
However, recently generated substance specific hazard data do not support the harmonised classification and labelling for this antimony compound as stated in Annex VI of regulation (EC) 1272/2008.
Therefore, an alternative proposal for the classification and labelling of sodium hexahydroxoantimonate based on substance specific data is provided as well.
Sodium Hexahydroxoantimonate (Representative sample)
| Classification |
|---|
Xn; R20/22 N; R51/53 |
| Labelling | |
|---|---|
| Indication of danger | Xn - harmful N - dangerous for the environment |
| R-phrases | R20/22 - harmful by inhalation and if swallowed R51/53 - toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment |
| S-phrases | S2 - keep out of the reach of children S61 - avoid release to the environment. refer to special instructions/safety data sheets |
| Notes | Note A, Note 1 |
Sodium Hexahydroxoantimonate (Representative sample) - proposed alternative classification
Remarks: Proposal for non-classification and labelling based on substance-specific, guideline-conform experimental data with unrestricted reliability as given in the technical dossier.
| Classification |
|---|
|
N; R51/53 |
| Labelling | |
|---|---|
| Indication of danger |
N - dangerous for the environment |
| R-phrases |
R51/53 - toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment |
| S-phrases |
S61 - avoid release to the environment. refer to special instructions/safety data sheets |





